Browsing by Author "Arancibia, Gloria"

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    Fluid-Assisted Aggregation and Assembly of Magnetite Microparticles in the Giant El Laco Iron Oxide Deposit, Central Andes
    (2023) Ovalle, J. Tomais; Reich, Martin; Barra, Fernando; Simon, Adam C.; Godel, Belinda; Le Vaillant, Margaux; Palma, Gisella; Deditius, Artur P.; Heuser, Gert; Arancibia, Gloria; Morata, Diego
    The El Laco iron oxide mineral deposit in the CentralAndes ofChile has attracted significant attention because of its uniquelypreserved massive magnetite orebodies, which bear a remarkable similarityto volcanic products. To date, the outcropping highly vesicular andporous massive magnetite orebodies have received little attentionfrom a microtextural point of view, limiting our understanding aboutthe role of volcanogenic processes on iron mineralization. Here, wereport the chemical composition of vesicular magnetite at El Lacousing EPMA and LA-ICP-MS methods and provide detailed 2D and 3D imagingof the internal structure of these texturally complex magnetite oresby combining SEM observations, synchrotron radiation micro-X-ray fluorescencechemical mapping, and high-resolution X-ray computed microtomography.Our observations reveal the presence of abundant magnetite microsphereswith diameters ranging from & SIM;100 to & SIM;900 & mu;m, aswell as dendritic microstructures forming interconnected networksup to a few millimeters in size. Two-dimensional microtextural andgeochemical imaging of the microspheres show that these features areformed by multiple euhedral magnetite crystals growing in all directionsand occur immersed within a porous matrix conformed by smaller-sized(& SIM;2-20 & mu;m) and irregularly shaped magnetite microparticles.These types of morphologies have been reported in hydrothermal ventsassociated with hydrovolcanic processes and commonly described inhydrothermal synthesis experiments of magnetite microspheres, suggestingprecipitation from iron-rich fluids. A hydrothermal origin for themagnetite microparticles reported here is further supported by theirgeochemical signature, which shows a strong depletion in most minorand trace elements typical from magnetite precipitated from hydrothermalfluids in ore-forming environments. We propose that decompression,cooling, and boiling of fluids triggered massive iron supersaturation,resulting in the nucleation of magnetite microparticles or colloids,followed by self-assembly into larger and more complex microstructures.Our data from El Laco deposit agree with models invoking magmatic-hydrothermalfluids to explain the origin of the deposit and provide new insightson the potential role of iron colloids as agents of mineralizationin volcanic systems.
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    Groundwater resources and recharge processes in the Western Andean Front of Central Chile
    (ELSEVIER, 2020) Taucare, Matias; Daniele, Linda; Viguier, Benoit; Vallejos, Angela; Arancibia, Gloria
    In Central Chile, the increment of withdrawals together with drought conditions has exposed the poor understanding of the regional hydrogeological system. In this study, we addressed theWestern Andean Front hydrogeology by hydrogeochemical and water stable isotope analyses of 23 springs, 10 boreholes, 5 rain-collectors and 5 leaching-rocks samples at Aconcagua Basin. From the upstream to the downstream parts of the Western Andean Front, most groundwater is HCO3-Ca and results from the dissolution of anorthite, labradorite and other silicate minerals. The Hierarchical Cluster Analysis groups the samples according to its position along the Western Andean Front and supports a clear correlation between the increasing groundwater mineralization (31-1188 mu S/cm) and residence time. Through Factorial Analysis, we point that Cl, NO3, Sr and Ba concentrations are related to agriculture practices in the Central Depression. After defining the regional meteoric water line at 33 degrees S in Chile, water isotopes demonstrate the role of rain and snowmelt above similar to 2000 m asl in the recharge of groundwater. Finally, we propose an original conceptual model applicable to the entire Central Chile. During dry periods, water releases fromhigh-elevation areas infiltrate in mid-mountain gullies feeding groundwater circulation in the fractured rocks of Western Andean Front. To the downstream, mountain-block and -front processes recharge the alluvial aquifers. Irrigation canals, conducting water from Principal Cordillera, play a significant role in the recharge of Central Depression aquifers. While groundwater in the Western Andean Front has a high-quality according to different water uses, intensive agriculture practices in the Central Depression cause an increment of hazardous elements for human-health in groundwater. (C) 2020 Elsevier B.V. All rights reserved.
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    Magmatism and Polyphase Deformation in the Middle Jurassic Arc of Central Chile: Implications for the Tectonic Development of the Early Andean Margin
    (2024) Singleton, John S.; Arancibia, Gloria; Morata, Diego; De La Maza, Ignacia Perez
    The similar to 173-164 Ma Papudo-Quintero plutonic complex near 32.5 degrees S in central Chile records three deformation events that provide insight into the tectonic development of the early Andean margin. The first event (D-1) includes: (a) high-temperature (>600 degrees C), coaxial-dominated strain along NE- to N-striking subvertical shear zones; (b) widespread emplacement of granitic dikes that dip gently to steeply NE; and (c) development of narrow (<10 cm thick) strike-slip and oblique-reverse shear zones. These D-1 structures record NW-SE to WNW-ESE transpressional shortening with a component of sinistral shear parallel to the N-S trending magmatic arc. Zircon and apatite U-Pb dates and cross-cutting relations constrain most D-1 deformation to similar to 166-164 Ma. The second event (D-2) occurred during postmagmatic cooling in the Late Jurassic and was characterized by development of pervasive E-W-striking veins with alteration halos and minor strike-slip and normal faults that record N-S extension in a transtensional regime. Structures associated with the last deformation event (D-3) include Late Jurassic to Early Cretaceous mafic dikes, veins, and conjugate strike-slip faults that record NW-SE to N-S shortening in a strike-slip regime. D-1 deformation is consistent with studies from other areas that document NW-SE shortening +/- sinistral transpression along the arc throughout the Jurassic, suggesting this deformation was regional in scale and driven by oblique subduction convergence. Deformation associated with oblique convergence was localized within the active magmatic arc, which was an important process in the early Andean orogeny. As the arc migrated eastward, D-2 and D-3 structures formed in a low-stress regime in an arc margin or forearc setting.
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    Multi-scale flow structure of a strike-slip tectonic setting: A self-similar model for the Liquine-Ofqui Fault System and the Andean Transverse Faults, Southern Andes (39-40 degrees S)
    (PERGAMON-ELSEVIER SCIENCE LTD, 2022) Roquer, Tomas; Arancibia, Gloria; Crempien, Jorge G. F.; Mery, Domingo; Rowland, Julie; Sepulveda, Josefa; Veloso, Eugenio E.; Nehler, Mathias; Bracke, Rolf; Morata, Diego
    The flow structure of a brittle crustal volume is defined by the multi-scale geometric and hydraulic properties of its fracture meshes. The length density distribution n(L,l) and the transmissivity distribution K(L,l) control the hydrologic scaling, where l is fracture length and L is the system size. The flow structure might display at most three key hydrologic scales: the connection scale, above which flow is focused in few critical paths; the channeling scale, above which flow is distributed in several paths; and the homogenization scale, above which permeability approaches a constant value. According to these scales, the hydrological structure could be distributed or clustered, thus having a clear impact in geothermal exploration campaigns and reservoir modeling. In this work, we determine the multi-scale flow structure for the Liquine-Ofqui Fault System (LOFS) and the Andean Transverse Faults (ATF) in the Southern Andes, by establishing the hydrologic scaling they follow. Using fractal statistics, we integrated geological data at the regional, meso-and micro-scale, including image analysis from X-ray microtomography. Our results suggest a self-similar, dense network with n(L,l)similar to l(-a) and a = 2.6-2.9, from the regional scale where the LOFS and ATF interact to the meso-and micro-scale within highly fractured areas of the LOFS. Scaling models are constrained by the length distribution, and other power-law functions reflecting the geometric arrangement of fractures, as well as the spatial distribution of superficial geothermal occurrences. Thus, we expect the hydrologic scaling to depend on the transmissivity distribution. Lognormal transmissivity distribution yields a permeability increase with scale, from the connection to the homogenization scales; whereas power-law transmissivity distribution yields a permeability increase from the connection scale without a limiting value. Approximations of the connection scale are around 10(-3)-10(0) m; the channeling scale, around 100-104 m; and if the homogenization scale exists, it should be equal or greater than 10(3)-10(4) m. Finally, the results presented here could to define the internal architecture of fracture meshes in fault-controlled fluid flow, and be used to select an appropriate hydrologic model according to the analyzed scale. Therefore, these findings must be taken into consideration in future geothermal prospecting, modeling and exploitation.
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    Numerical modeling of the Nevados de Chillan fractured geothermal reservoir
    (2025) Oyarzo-Cespedes, Isa; Arancibia, Gloria; Browning, John; Crempien, Jorge G. F.; Morata, Diego; Mura, Valentina; Lopez-Contreras, Camila; Maza, Santiago
    Numerical models can be utilized to understand and anticipate the future behavior of a geothermal reservoir, and hence aid in the development of efficient reservoir engineering strategies. However, as each system has a unique geological context, individual characterization is required. In this research, the Nevados de Chillan Geothermal System (NChGS) in the Southern Volcanic Zone of the Andes is considered. The NChGS is controlled by the geology of the active Nevados de Chillan Volcanic Complex (NChVC) including their basement units (Miocene lavas and volcaniclastic layers from Cura-Mall & iacute;n Formation and the Miocene, Santa Gertrudis granitoids) as well as the key structural control from crustal scale faults, all of which combine to influence the reservoir characteristics. The presence of faults acts to generate a high secondary permeability which favors the circulation of hydrothermal fluids. Based on previous studies in the NChGS, we designed a thermo-hydraulic model in COMSOL Multiphysics (R) combining equations of heat transfer and Darcy's law in order to determine the distribution of isotherms and surface heat flux. The boundary conditions of the model were informed by a conceptual model of depth 3 km and width of 6.6 km which considers a highly fractured granitic reservoir, a clay cap behavior of Miocene lavas and volcaniclastic units, and transitional zones between a regional zone and the reservoir. A lowangle reverse fault affecting the clay cap unit was also incorporated into the models. Results indicate convective behavior in the reservoir zone and a surface heat flux of 0.102 W/m2 with a local peak up to 0.740 W/m2 in the area affected by the low-angle reverse fault zone. The models suggest hydrothermal fluid residence times of around 9-15 thousand years are required to reach a steady-state thermal configuration, which is consistent with the deglaciation age proposed for the NChVC latitude of the complex (c. 10-15 ka). Permeability in the fractured reservoir is one of the most complex parameters to estimate and the most sensitive and hence requires further constraint. Finally, using the volumetric method and the results obtained in this research, we estimate a geothermal potential of 39 +/- 1 MWe for the NChGS.
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    Peraluminous Grenvillian TTG in the Sierra de Pie de Palo, Western Sierras Pampeanas, Argentina: Petrology, geochronology, geochemistry and petrogenetic implications
    (ELSEVIER, 2010) Morata, Diego; Castro de Machuca, Brigida; Arancibia, Gloria; Pontoriero, Sandra; Fanning, C. Mark
    Combined petrological, geochemical, isotopic and geochronological data shed light on the origin and evolution of a peraluminous garnet-bearing two-mica granitoid (El Tigre Granitoid: ETG) cropping out in southwestern Sierra de Pie de Palo (31 degrees 31'30 '' S-68 degrees 15'12 '' W), and to constrain the age and petrogenetic conditions of this intrusive event. ETG experienced amphibolite to greenschist facies metamorphism after igneous crystallization, followed by strong deformation restricted to narrow mylonite zones (ETG shear zone) and partial dynamic recrystallization under lower-T conditions. A dextral shear sense is compatible with kinematic observations registered along the NNE striking regional Las Pirquitas overthrust, active at 473 +/- 10 Ma (K/Ar on <2 mu m micaceous fraction for the ETG shear zone). The ETG crops out as small, tabular to lenticular vein-like bodies emplaced into metasedimentary rocks of the Pie de Palo Complex. The ETG ranges from granodiorite to tonalite, with a moderately peraluminous signature (ASI = 1.09-1.33; A/CNK >1.1; normative corundum; low CaO values between 1.72 and 2.41%), plotting mostly in the granite-trondhjemite fields of the Ab-An-Or diagram. The trace element contents show a relatively low abundance of Rb, HFS elements such as Y, Nb, Ta, Ga and Zr, and high concentrations of Ba, Sr, and Sigma LREE. The chondrite-normalized REE pattern has a high slope with [La/Yb](N) = 9.48-55.32 and a negative or absent europium anomaly. Relationships between trace elements suggest the classical setting of granitoids produced in a convergent plate setting.
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    Selective reactivation of inherited fault zones driven by stress field changes: Insights from structural and paleostress analysis of the Pocuro Fault Zone, Southern Central Andes (32.8 degrees S)
    (PERGAMON-ELSEVIER SCIENCE LTD, 2022) Taucare, Matias; Roquer, Tomas; Heuser, Gert; Perez-Estay, Nicolas; Arancibia, Gloria; Yanez, Gonzalo; Viguier, Benoit; Figueroa, Ronny; Morataa, Diego; Daniele, Linda
    This study aims to explain the selective reactivation of normal faults during the Andean orogeny at the Southern Central Andes western flank. We conducted a structural mapping and paleostress field reconstruction in the regional-scale Pocuro Fault Zone (PFZ) at 32.8 degrees S. Results reveal that the architecture of the PFZ results from at least two deformation phases, each revealing an individual progressive and gradual evolution. The earliest deformation phase is recorded by two similar to NS-striking normal faults involving a 5 km wide damage zone characterized by quartz-laumontite and calcite veins that were developed under an extensional regime with a WNW-ESE-trending sigma 3-axis. The latest deformation phase is recorded by one NS-striking reverse-dextral fault with goethite-hematite syn-tectonic precipitation and two NW-striking reverse-sinistral faults. Reverse faults were developed under a compressional/transpressional regime characterised by an ENE-WSW-trending sigma 1-axis with a sigma 2-/sigma 3-axis permutation. From a geophysical data reassessment, we inferred that observed faults in the surface within the PFZ are regional-scale deep-seated structures. Considering previous geochronological data, we correlated the earliest and latest phases with the Abanico Basin extension (middle Eocene-early Miocene) and its subsequent inversion (Miocene). Given the neotectonic evidence (geomorphic markers and deformation of unconsolidated deposits), the latter phase likely remains active. Quartz-laumontite cementation of the fault core's cataclastic material promotes mechanical strengthening leading to negative feedback for the reactivation of inherited normal faults as reverse ones. Conversely, the concentration of fractures in the damage zone between the normal faults promotes mechanical weakening resulting in a preferential area for the propagation of reverse fault during the compressive/transpressional phase.