Browsing by Author "Cardero, Yaniel"

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    Design of an antioxidant powder additive based on carvacrol encapsulated into a multilayer chitosan-alginate-maltodextrin emulsion
    (2024) Cardero, Yaniel; Aguirre-Calvo, Tatiana Rocio; Valenzuela, Loreto M.; Matiacevich, Silvia; Santagapita, Patricia Roman
    Carvacrol has demonstrated antioxidant activity; however, its high volatility and low water solubility limit its direct application in food matrices. Then, an effective encapsulation system is required to protect it. This study aimed to design and characterize a carvacrol-based additive encapsulated in a spray-dried multilayer emulsion based on chitosan/sodium alginate/maltodextrin. Spray-drying temperature of 120 degrees C and 3 %(w/w) maltodextrin content maximized both encapsulation efficiency (similar to 97 %) and loading capacity (similar to 53 %). The powder's antioxidant properties were evaluated in two food simulant media: water (SiW) and water-ethanol (SiD). The highest antioxidant activity was observed in SiW for both ABTS(center dot+) (8.2 +/- 0.3mg(EAG)/g) and FRAP (4.1 +/- 0.2mg(EAG)/g) methods because of the reduced release of carvacrol in SiD vs. SiW, as supported by micro- and macrostructural observations by SAXS and microscopy, respectively. An increase from 143 to 157 degrees C attributable to carvacrol protection and T-g = 44.4 degrees C (> ambient) were obtained by TGA and DSC, respectively. FT-IR confirmed intermolecular interactions (e.g. -COO- and -NH3+) as well as H-bonding formation. High water solubility (81 +/- 3 %), low hygroscopicity (8.8 +/- 0.2 %(w/w), poor flowability (CI:45 +/- 4), and high cohesiveness (HR:1.8 +/- 0.1) between particles were achieved, leading to a powdered antioxidant additive with high potential for applications which required avoiding/reducing oxidation on hydrophilic and hydrophobic food products.
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    Eco-Friendly Design of Chitosan-Based Films with Biodegradable Properties as an Alternative to Low-Density Polyethylene Packaging
    (2024) Fiallos-Nunez, Johanna; Cardero, Yaniel; Cabrera-Barjas, Gustavo; Garcia-Herrera, Claudio M.; Inostroza, Matias; Estevez, Miriam; Espana-Sanchez, Beatriz Liliana; Valenzuela, Loreto M.
    Biopolymer-based films are a promising alternative for the food packaging industry, in which petrochemical-based polymers like low-density polyethylene (LDPE) are commanding attention because of their high pollution levels. In this research, a biopolymer-based film made of chitosan (CS), gelatin (GEL), and glycerol (GLY) was designed. A Response Surface Methodology (RSM) analysis was performed to determine the chitosan, gelatin, and glycerol content that improved the mechanical properties selected as response variables (thickness, tensile strength (TS), and elongation at break (EAB). The content of CS (1.1% w/v), GEL (1.1% w/v), and GLY (0.4% w/v) in the film-forming solution guarantees an optimized film (OPT-F) with a 0.046 +/- 0.003 mm thickness, 11.48 +/- 1.42 mPa TS, and 2.6 +/- 0.3% EAB. The OPT-F was characterized in terms of thermal, optical, and biodegradability properties compared to LDPE films. Thermogravimetric analysis (TGA) revealed that the OPT-F was thermally stable at temperatures below 300 degrees C, which is relevant to thermal processes in the food industry of packaging. The reduced water solubility (WS) (24.34 +/- 2.47%) and the improved biodegradability properties (7.1%) compared with LDPE suggests that the biopolymer-based film obtained has potential applications in the food industry as a novel packaging material and can serve as a basis for the design of bioactive packaging.