PALLADIUM COMPLEX BEARING 3,5-BIS(BENZOTRIAZOL-1-YLMETHYL) TOLUENE LIGAND CATALYZES OXIDATIVE AMINATION OF ALLYL BUTYL ETHER

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dc.contributor.authorHurtado, John
dc.contributor.authorRojas, Rene S.
dc.contributor.authorPerez, Edwin G.
dc.contributor.authorValderrama, Mauricio
dc.date.accessioned2025-01-24T00:04:57Z
dc.date.available2025-01-24T00:04:57Z
dc.date.issued2013
dc.description.abstractThe reaction of 3,5-bis(bromomethyl)toluene with benzotriazole yields the bidentate ligand 3,5-bis(benzotriazol-1-ylmethyl)toluene (1). This ligand reacts with [PdCl2(cod)] (cod = 1,5-cyclooctadiene) to give the complex [PdCl2{3,5-bis(benzotriazol-1-ylmethyl)tolyl}] (2). These compounds were characterized by elemental analyses, mass spectra, and FTIR and NMR (H-1, C-13) spectroscopies. The palladium(II) complex 2 shows high activity as catalyst for oxidative amination, involving allyl butyl ether and phthalimide as substrates and PhICl2 as a stoichiometric oxidant.
dc.fuente.origenWOS
dc.identifier.issn0717-9707
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/101821
dc.identifier.wosidWOS:000331236900007
dc.issue.numero1
dc.language.isoen
dc.pagina.final1536
dc.pagina.inicio1534
dc.revistaJournal of the chilean chemical society
dc.rightsacceso restringido
dc.subjectPalladium complex
dc.subjectBidentate nitrogen ligand
dc.subjectAminopalladation
dc.subjectOxidative amination
dc.titlePALLADIUM COMPLEX BEARING 3,5-BIS(BENZOTRIAZOL-1-YLMETHYL) TOLUENE LIGAND CATALYZES OXIDATIVE AMINATION OF ALLYL BUTYL ETHER
dc.typeartículo
dc.volumen58
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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