Synthesis of <i>N</i>-arylsulfonamides via Chan-Lam Coupling Between Aryl Boronic Acids and <i>N</i>-[(sulfonyl)imino]phenyliodinanes

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dc.contributor.authorMerchan-Arenas, Diego R.
dc.contributor.authorRivero-Jerez, Paula S.
dc.contributor.authorPerez, Edwin G.
dc.date.accessioned2025-01-20T22:04:15Z
dc.date.available2025-01-20T22:04:15Z
dc.date.issued2021
dc.description.abstractWe synthesized a library of 32 sulfonamides via CuBr2 catalyzed Chan-Lam C-N coupling, reaching excellent yields (until 81 %) under ligand-base-free, mild conditions, and short reaction times. A new non-toxic, versatile and easy to prepare starting materials, N-[(Sulfonyl)imino]phenyliodinanes were first time proposed as the nitrogen source in this synthetic tool. Finally, the sulfonamides were used as valuable building blocks in the synthesis of mono-alkyl anilines through their alkylation and Fukuyama deprotection steps.
dc.fuente.origenWOS
dc.identifier.doi10.1002/slct.202103876
dc.identifier.issn2365-6549
dc.identifier.urihttps://doi.org/10.1002/slct.202103876
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/94074
dc.identifier.wosidWOS:000726827000026
dc.issue.numero45
dc.language.isoen
dc.pagina.final12810
dc.pagina.inicio12806
dc.revistaChemistryselect
dc.rightsacceso restringido
dc.subjectChan-Lam C-N coupling
dc.subjectIodinanes
dc.subjectN-aryl sulfonamides
dc.subjectmonoalkyl anilines
dc.titleSynthesis of <i>N</i>-arylsulfonamides via Chan-Lam Coupling Between Aryl Boronic Acids and <i>N</i>-[(sulfonyl)imino]phenyliodinanes
dc.typeartículo
dc.volumen6
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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