New mono and bimetallic iron complexes derived from partially methylated <i>s</i>-indacene. Evidence of a trinuclear iron <i>s</i>-indacene complex

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dc.contributor.authorMorales-Verdejo, Cesar
dc.contributor.authorMartinez-Diaz, Ivan
dc.contributor.authorAdams, Christopher
dc.contributor.authorAraneda, Juan Felipe
dc.contributor.authorOehninger, Luciano
dc.contributor.authorCarey, Desmond Mac-Leod
dc.contributor.authorMunoz-Castro, Alvaro
dc.contributor.authorArratia-Perez, Ramiro
dc.contributor.authorChavez, Ivonne
dc.contributor.authorManuel Manriquez, Juan
dc.date.accessioned2025-01-23T21:47:37Z
dc.date.available2025-01-23T21:47:37Z
dc.date.issued2014
dc.description.abstractThe preparation and characterization of new mono- and multinuclear iron complexes derived from s-indacene partially alkylated has been achieved by the development of rational synthetic routes. The synthesis of the new multimetallic complexes are based on the employment of 1,5-dihydro-2,4,6, 8-tetramethyl-s-indacene (Ic'H-2) as ligand to obtain two monometallic complexes, namely, [Cp*-Fe-(eta(5)-2,4,6,8-tetramethyl-5-hydro-s-indacenide)] (1), and [Fe-bis(eta(5)-2,4,6,8-tetramethyl-5-hydro-s-indacenide)] (2) (Cp* = pentamethylcyclopentadiene), as well as, the new bimetallic [Cp*Fe-(mu:eta(5):eta(5)-2,4,6,8-tetramethyl-s-indaceneiide)-FeCp*] (3) and trimetallic [Fe-bis{Cp*Fe-(mu:eta(5):eta(5)-2,4,6,8-tetramethyl-s-indaceneiide)}] (4) complexes. All complexes here reported were characterized by means of H-1, C-13 NMR, mass spectrometry, elemental analysis, together with cyclic voltammetry. In addition, these complexes have been studied by DFT methods in order to gain further knowledge about its electronic structure. In addition, the possibility to generate organometallic polymers employing the complexes here reported, is proposed theoretically with the study of an oligomer titled as [Cp*(Fe(Ic')}(4)FeCp*], 6(t). (C) 2013 Elsevier Ltd. All rights reserved.
dc.fuente.origenWOS
dc.identifier.doi10.1016/j.poly.2013.11.023
dc.identifier.issn0277-5387
dc.identifier.urihttps://doi.org/10.1016/j.poly.2013.11.023
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/101744
dc.identifier.wosidWOS:000331502500003
dc.language.isoen
dc.pagina.final24
dc.pagina.inicio15
dc.revistaPolyhedron
dc.rightsacceso restringido
dc.subjectOrganometallic
dc.subjectBimetallic complexes
dc.subjectTrimetallic complex
dc.subjectDFT
dc.subject.ods12 Responsible Consumption and Production
dc.subject.odspa12 Producción y consumo responsable
dc.titleNew mono and bimetallic iron complexes derived from partially methylated <i>s</i>-indacene. Evidence of a trinuclear iron <i>s</i>-indacene complex
dc.typeartículo
dc.volumen69
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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