Surface characterization and study of Langmuir films of poly(4-vinylpyridine) quaternized with n-alkylbromide
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Date
2001
Journal Title
Journal ISSN
Volume Title
Publisher
JOHN WILEY & SONS LTD
Abstract
The surface behaviour of poly(4-vinylpyridine)s (P4VP) quaternized with four different alkyl chains (pentyl, hexyl, octyl and decy bromide) were studied. Surface pressure-area isotherms (pi -A) at the air-water interface were determined. Depending on the length of the side-chains, the pi -A isotherms show a plateau region. An extensive plateau is observed for n >6. The plateau pressures are similar for n = 8 and n = 10. The monolayers are stable and exhibit hysteresis phenomena. Brewster angle microscopy (BAM) is used to monitor the monolayer topography of the polymer on water subphase. To obtain information about the surface energy (SE) and the degree of hydrophobicity of these systems, we have estimated the critical surface tension, gamma (c), and the dispersion force and polar contributions to SE, gamma (D) and gamma (P), respectively, by measurements of the contact angle (CA) of water and bromobenzene on the polymer surface. The results obtained are depend on the length of the alkyl lateral chain of the functionalized polymers. (C) 2001 Society of Chemical Industry.
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Keywords
Langmuir films, poly(4-vinylpyridine)s quaternized, surface-area isotherms, Brewster angle microscopy, monolayers, contact angle, MONOLAYERS, INTERFACE, POLYMERS, MICELLES