Novel Hydrophobic Functionalized UiO-66 Series: Synthesis, Characterization, and Evaluation of Their Structural and Physical-Chemical Properties

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dc.contributor.authorNarea, Pilar
dc.contributor.authorBrito, Ivan
dc.contributor.authorQuintero, Yurieth
dc.contributor.authorCamu, Esteban
dc.date.accessioned2025-01-20T17:10:23Z
dc.date.available2025-01-20T17:10:23Z
dc.date.issued2024
dc.description.abstractA novel set of four functionalized hydrophobic UiO-66-NHR series were synthesized through postsynthetic procedures, utilizing various benzoyl chlorides and UiO-66-NH2 as starting materials. This synthesis method was carried out by employing p- (1) and o-toluoyl (2), as well as 2- (3) and 4-fluorobenzoyl (4) substituents. The analysis of the resulting compounds was performed using conventional spectroscopic methods such as FT-IR and 1H NMR to quantify the conversion rate into amide. Furthermore, SEM and XPS techniques were employed for morphological and surface analysis. Finally, the evaluation of the chemical stability and contact angle using the sessile drop method was performed to evaluate the technological potential of these compounds for application in aqueous and acidic media (such as selective separation of different metals and wastewater recovery).
dc.fuente.origenWOS
dc.identifier.doi10.3390/ijms25010199
dc.identifier.eissn1422-0067
dc.identifier.issn1661-6596
dc.identifier.urihttps://doi.org/10.3390/ijms25010199
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/91104
dc.identifier.wosidWOS:001140393100001
dc.issue.numero1
dc.language.isoen
dc.revistaInternational journal of molecular sciences
dc.rightsacceso restringido
dc.subjecthydrophobic MOFs
dc.subjectpost-synthetic methods
dc.subjectaqueous media
dc.subjectacid media
dc.titleNovel Hydrophobic Functionalized UiO-66 Series: Synthesis, Characterization, and Evaluation of Their Structural and Physical-Chemical Properties
dc.typeartículo
dc.volumen25
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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