Catalytic activity and visible spectroscopy of [Rh(norbornadiene)Cl]2/p-RC6H4)3P system in methanol
dc.contributor.author | Santos, José G. | |
dc.date.accessioned | 2019-12-28T02:45:18Z | |
dc.date.available | 2019-12-28T02:45:18Z | |
dc.date.issued | 1984 | |
dc.description.abstract | The catalytic hydrogenation of hex-1-ene in methanolic solution with [Rh(norbornadiene)Cl]2/(p-RC6H4)3 P (R=H, Me or OMe) systems preparedin situ has been measured. The catalytic activity shows a dependence on the ageing of the catalyst precursor solution in the presence of air. A spectroscopic study (visible region) has been carried out for the system with triphenyl phosphine and shows degradation with the formation of [Rh(norbornadiene)PPh3Cl] as an intermediate. It was demonstrated that the spectral changes and the consequent catalytic activity are due to PPh3 loss because of the oxygen dissolved in the media. | |
dc.format.extent | 3 páginas | |
dc.fuente.origen | Springer | |
dc.identifier.doi | 10.1007/BF00935933 | |
dc.identifier.uri | https://doi.org/10.1007/BF00935933 | |
dc.identifier.uri | https://repositorio.uc.cl/handle/11534/27092 | |
dc.issue.numero | No. 4 | |
dc.language.iso | en | |
dc.pagina.final | 157 | |
dc.pagina.inicio | 155 | |
dc.revista | Transition Metal Chemistry | es_ES |
dc.rights | acceso restringido | |
dc.subject | Oxygen | es_ES |
dc.subject | Hydrogenation | es_ES |
dc.subject | Spectroscopy | es_ES |
dc.subject | Methanol | es_ES |
dc.subject | Catalysis | es_ES |
dc.subject.ddc | 510 | |
dc.subject.dewey | Matemática física y química | es_ES |
dc.subject.ods | 12 Responsible consuption and production | |
dc.subject.odspa | 12 Producción y consumo responsable | |
dc.title | Catalytic activity and visible spectroscopy of [Rh(norbornadiene)Cl]2/p-RC6H4)3P system in methanol | es_ES |
dc.type | artículo | |
dc.volumen | Vol. 9 | |
sipa.codpersvinculados | 98813 |