Vinyltrimethylsilane-co-methylmethacrylate copolymers. Synthesis and reactivity ratios

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dc.contributor.authorGatica, N
dc.contributor.authorAlegria, S
dc.contributor.authorTagle, LH
dc.contributor.authorDiaz, F
dc.contributor.authorGargallo, L
dc.contributor.authorRadic, D
dc.date.accessioned2024-01-10T13:09:54Z
dc.date.available2024-01-10T13:09:54Z
dc.date.issued2000
dc.description.abstractIn order to obtain information about the copolymerization process of vinyltrimethyl silane with comonomers of different chemical structure, copolymers containing vinyltrimethylsilane and methyl methacrylate at different compositions were synthesized and characterized. Comparison of the reactivity ratios of the resulting copolymers with those containing N-vinyl-2-pyrrolidone and 2-vinylpyridine previously reported and other related comonomers with different chemical structure allows us to establish some reactivity structure relationship and a generalization for these systems. The monomer reactivity ratios r(1) and r(2) (MRR) were estimated by using the classical linear fitting procedures and also through a computer program based on a nonlinear minimization algorithm, starting from the r(1) and r(2) values obtained by the former procedures.
dc.fechaingreso.objetodigital2024-05-09
dc.format.extent7 páginas
dc.fuente.origenWOS
dc.identifier.doi10.1081/MA-100102333
dc.identifier.issn1060-1325
dc.identifier.urihttps://doi.org/10.1081/MA-100102333
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/77710
dc.identifier.wosidWOS:000166113600009
dc.information.autorucQuímica;Díaz F;S/I;98205
dc.information.autorucQuímica;Gargallo L;S/I;98194
dc.information.autorucQuímica;Radic D;S/I;49367
dc.information.autorucQuímica;Tagle L;S/I;49327
dc.issue.numero12
dc.language.isoen
dc.nota.accesocontenido parcial
dc.pagina.final1683
dc.pagina.inicio1677
dc.publisherMARCEL DEKKER INC
dc.revistaJOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
dc.rightsacceso restringido
dc.titleVinyltrimethylsilane-co-methylmethacrylate copolymers. Synthesis and reactivity ratios
dc.typeartículo
dc.volumen37
sipa.codpersvinculados98205
sipa.codpersvinculados98194
sipa.codpersvinculados49367
sipa.codpersvinculados49327
sipa.indexWOS
sipa.trazabilidadCarga SIPA;09-01-2024
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