Pentamethylcyclopentadienyliridium(III) complexes containing tertiary phosphorus chalcogenide ligands: Crystal structure of [(eta(5)C(5)Me(5))Ir{PO(OMe)(2)}{eta(2)(SPPh(2))(2)CH2-S,S'}]BF4 center dot 0.5Me(2)CO

Simple item page
dc.contributor.authorValderrama, M
dc.contributor.authorContreras, R
dc.date.accessioned2025-01-21T01:34:02Z
dc.date.available2025-01-21T01:34:02Z
dc.date.issued1996
dc.description.abstractNeutral iridium(III) complexes of the unidentate P-donor ligands dppm, dppmS and dppmSe, and cationic complexes with these ligands acting in their bidentate form have been prepared and characterized. Similar cationic complexes with the symmetrical bidentate dichalcogenide ligands dppmS, and dppmSe, have been described. These compounds react with sodium hydride in tetrahydrofuran or with thallium pyrazolate in dichloromethane to yield the new cationic complexes [(eta(5)C(5)Me(5))Ir{eta(3)(EPPh(2))(2)CH-C,E,E'}](+) (E = S, Se) in which the anionic methanide dichalcogenide ligand is acting as a tripod ligand with a C,E,E'-donor set. However, the complexes [(eta(5)C(5)Me(5))IrCl(eta(2)dppmE(2))]BF4 react with P(OMe)(3) in the presence of TIBF4, to give the dicationic compounds [(eta(5)C(5)Me(5))Ir{P(OMe>(3)}(eta(2)dppmE(2))(BF4)(2). In these complexes, the P(OMe)(3) ligand is transformed into a coordinated PO(OMe)(2) group by reaction with sodium iodide in acetone. The structure of the complex [(eta(5)C(5)Me(5))Ir{PO(OMe)(2)}(eta(2)dppmS(2)-S,S')]BF4 . 0.5Me(2)CO have been determined by single crystal X-ray diffraction methods.
dc.fuente.origenWOS
dc.identifier.issn0022-328X
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/97505
dc.identifier.wosidWOS:A1996UP36400002
dc.issue.numero1-2
dc.language.isoen
dc.pagina.final15
dc.pagina.inicio7
dc.revistaJournal of organometallic chemistry
dc.rightsacceso restringido
dc.subjectiridium
dc.subjectcyclopentadienyl complexes
dc.subjecttertiary chalcogenides
dc.subjectphosphonate complexes
dc.subject.ods12 Responsible Consumption and Production
dc.subject.odspa12 Producción y consumo responsable
dc.titlePentamethylcyclopentadienyliridium(III) complexes containing tertiary phosphorus chalcogenide ligands: Crystal structure of [(eta(5)C(5)Me(5))Ir{PO(OMe)(2)}{eta(2)(SPPh(2))(2)CH2-S,S'}]BF4 center dot 0.5Me(2)CO
dc.typeartículo
dc.volumen513
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
Files
Collections
Artículos de revistas