Study of the reaction mechanism in hydrogen production using metal-free Schiff base as a catalyst

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dc.contributor.authorMuena, Juan Pablo
dc.contributor.authorZamora, Pedro Pablo
dc.contributor.authorBieger, Klaus
dc.contributor.authorSoliz, Alvaro
dc.contributor.authorHaribabu, Jebiti
dc.contributor.authorAguirre, Maria Jesus
dc.contributor.authorMarquez, Paulina
dc.contributor.authorQuezada, Diego
dc.contributor.authorHonores, Jessica
dc.date.accessioned2025-01-20T17:20:59Z
dc.date.available2025-01-20T17:20:59Z
dc.date.issued2023
dc.description.abstractUnderstanding the hydrogen evolution reaction and its mechanism is crucial for numerous practical applications in the realm of green energy. The development and discovery of new technologies or alternatives hold great significance in generating hydrogen at a low cost. In this study, we propose a novel catalyst, N, N'-bis(2-hydroxy1-naphthaldehyde)-o-phenylenediamine ([naph]2-o-ph), which is a Schiff base, for hydrogen production. The novelty lies in utilizing the organic Schiff base system and the proposed mechanism for hydrogen evolution, involving protonation and electron exchange on the Schiff base. Both experimental and theoretical results highlight the high capability of the Schiff base in generating hydrogen, providing valuable insights for potential applications in water electrolysis.
dc.fuente.origenWOS
dc.identifier.doi10.1016/j.molliq.2023.123207
dc.identifier.eissn1873-3166
dc.identifier.issn0167-7322
dc.identifier.urihttps://doi.org/10.1016/j.molliq.2023.123207
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/91443
dc.identifier.wosidWOS:001126043600001
dc.language.isoen
dc.revistaJournal of molecular liquids
dc.rightsacceso restringido
dc.subjectHydrogen production
dc.subjectSchiff base
dc.subjectCatalyst
dc.subjectDFT calculations
dc.subjectMechanistic studies
dc.subject.ods07 Affordable and Clean Energy
dc.subject.odspa07 Energía asequible y no contaminante
dc.titleStudy of the reaction mechanism in hydrogen production using metal-free Schiff base as a catalyst
dc.typeartículo
dc.volumen391
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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