Solubility of carotenoid pigments (lycopene and astaxanthin) in supercritical carbon dioxide

dc.contributor.authorde la Fuente, Juan C.
dc.contributor.authorOyarzun, Bernardo
dc.contributor.authorQuezada, Nathalie
dc.contributor.authordel Valle, Jose M.
dc.date.accessioned2024-01-10T12:08:40Z
dc.date.available2024-01-10T12:08:40Z
dc.date.issued2006
dc.description.abstractThis contribution provides basic data for developing an extraction process for carotenoid compounds in terrestrial and marine plants with supercritical CO2 (SC-CO2). Specifically, the solubility (y(2), molar fraction) of lycopene and astaxanthin was measured in SC-CO2 as a function of temperature (313 K <= T <= 333 K) and pressure (10 MPa <= P <= 42 MPa). Experimental data were correlated using a density-based model valid for a solvent density above 330kg/m3. Based on this model and the best-fit model parameters, the solubility of lycopene in SC-CO2 at 313 K and 30 MPa (y(2) = 0.40 x 10(-6)) was within a wide range of experimental values for the solubility of beta-carotene in CO2 under same conditions (0.20 x 10(-6) <= y(2) <= 0.50 x 10-6). The interpolated solubility of astaxanthin in SC-CO2 at 313 K and 30 MPa was slightly smaller (y(2) = 0.19 x 10(-6)) than the one of lycopene, as expected for a slightly heavier and more polar solute. There was a larger increase in solubility of both lycopene and astaxanthin by increasing the temperature from 313 to 333 K at a constant pressure of 30 MPa (2.8-5.1 times) than by increasing the pressure from 30 to 50 MPa at a constant temperature of 313 K (1.3-1.6 times), which was consistent with the trend in literature for the solubility of beta-carotene in SC-CO2. (c) 2006 Elsevier B.V. All rights reserved.
dc.fechaingreso.objetodigital25-03-2024
dc.format.extent6 páginas
dc.fuente.origenWOS
dc.identifier.doi10.1016/j.fluid.2006.05.031
dc.identifier.issn0378-3812
dc.identifier.urihttps://doi.org/10.1016/j.fluid.2006.05.031
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/76416
dc.identifier.wosidWOS:000240563000012
dc.information.autorucIngeniería;Del Valle J;S/I;57259
dc.issue.numero1-2
dc.language.isoen
dc.nota.accesocontenido parcial
dc.pagina.final95
dc.pagina.inicio90
dc.publisherELSEVIER SCIENCE BV
dc.revistaFLUID PHASE EQUILIBRIA
dc.rightsacceso restringido
dc.subjectastaxanthin
dc.subjectcarotenoid pigments
dc.subjectcarbon dioxide
dc.subjectdensity correlation
dc.subjectlycopene
dc.subjectsolubility
dc.subjectBETA-CAROTENE
dc.subjectCO2 EXTRACTION
dc.subjectNITROUS-OXIDE
dc.subjectFATTY-ACIDS
dc.subjectCOMPONENTS
dc.subjectSEPARATION
dc.subjectMICROALGAE
dc.subjectCAPSAICIN
dc.subjectBEHAVIOR
dc.subjectFLUIDS
dc.titleSolubility of carotenoid pigments (lycopene and astaxanthin) in supercritical carbon dioxide
dc.typeartículo
dc.volumen247
sipa.codpersvinculados57259
sipa.indexWOS
sipa.indexScopus
sipa.trazabilidadCarga SIPA;09-01-2024
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