N,N ' and N,O chelated phosphenium cations containing aminotroponiminate or aminotroponate units

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dc.contributor.authorPop, Lucian Cristian
dc.contributor.authorKatir, Nadia
dc.contributor.authorCastel, Annie
dc.contributor.authorSilaghi Dumitrescu, Luminita
dc.contributor.authorDelpech, Fabien
dc.contributor.authorSilaghi Dumitrescu, Ioan
dc.contributor.authorGornitzka, Heinz
dc.contributor.authorMacLeod Carey, Desmond
dc.contributor.authorSaffon, Nathalie
dc.date.accessioned2024-01-10T12:40:53Z
dc.date.available2024-01-10T12:40:53Z
dc.date.issued2009
dc.description.abstractNew phosphenium cations stabilized by bidentate monoanionic N-isopropyl-2-(isopropylamino)troponiminate or 2-(isopropylamino)troponate units have been synthesized. These complexes were characterized by P-31, H-1 and C-13 NMR spectroscopies, and the molecular structures were determined by X-ray crystallography. These data indicate the formation of N,N'- and N,O-chelate derivatives having three-coordinate phosphorous atoms included in planar heterobicycles. Moreover, computational studies support the presence of high delocalization of the positive charge into the pi-conjugated carbon backbone and of the high-lying phosphorus lone-pair orbital. (c) 2009 Elsevier B.V. All rights reserved.
dc.description.funderECONET Program
dc.description.funder"Le comite mixte interuniversitaire franco-marocain"
dc.fechaingreso.objetodigital27-03-2024
dc.format.extent5 páginas
dc.fuente.origenWOS
dc.identifier.doi10.1016/j.jorganchem.2009.01.022
dc.identifier.eissn1872-8561
dc.identifier.issn0022-328X
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2009.01.022
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/77358
dc.identifier.wosidWOS:000264637400044
dc.information.autorucQuímica;MacLeod-Carey D;S/I;158167
dc.issue.numero9-10
dc.language.isoen
dc.nota.accesocontenido parcial
dc.pagina.final1566
dc.pagina.inicio1562
dc.publisherELSEVIER SCIENCE SA
dc.revistaJOURNAL OF ORGANOMETALLIC CHEMISTRY
dc.rightsacceso restringido
dc.subjectPhosphorus
dc.subjectN,N ligand
dc.subjectN,O ligand
dc.subjectChelates
dc.subjectCOORDINATE PHOSPHORUS ATOMS
dc.subjectCOMPLEXES
dc.subjectAPPROXIMATION
dc.subjectAROMATICITY
dc.subjectDERIVATIVES
dc.subjectREACTIVITY
dc.subjectCHEMISTRY
dc.subjectGERMANIUM
dc.subjectCATALYSTS
dc.subjectLIGANDS
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa03 Salud y bienestar
dc.titleN,N ' and N,O chelated phosphenium cations containing aminotroponiminate or aminotroponate units
dc.typeartículo
dc.volumen694
sipa.codpersvinculados158167
sipa.indexWOS
sipa.indexScopus
sipa.trazabilidadCarga SIPA;09-01-2024
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