Nickel alpha-Keto-beta-Diimine Initiators for Olefin Polymerization

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dc.contributor.authorAzoulay, Jason D.
dc.contributor.authorRojas, Rene S.
dc.contributor.authorSerrano, Abigail V.
dc.contributor.authorOhtaki, Hisashi
dc.contributor.authorGalland, Griselda B.
dc.contributor.authorWu, Guang
dc.contributor.authorBazan, Guillermo C.
dc.date.accessioned2024-01-10T12:06:55Z
dc.date.available2024-01-10T12:06:55Z
dc.date.issued2009
dc.description.abstract(Figure Presented) A new ligand-metal combination (see picture, Ni green, Br brown, N blue, O red, C gray) was designed to be cationic and to benefit from removal of electron density by the action of a Lewis acid on the ligand framework. In the presence of various activators, the resulting catalytic site is highly active for ethylene polymerization and capable of polymerizing α-olefins to high molecular weights. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
dc.description.funderMC-CAM
dc.description.funderR.S.R
dc.description.funderA.V.S
dc.description.funderFONDECYT
dc.description.funderDirect For Mathematical & Physical Scien
dc.description.funderDivision Of Materials Research
dc.format.extent4 páginas
dc.fuente.origenWOS
dc.identifier.doi10.1002/anie.200804661
dc.identifier.eissn1521-3773
dc.identifier.issn1433-7851
dc.identifier.pubmedidMEDLINE:19065683
dc.identifier.urihttps://doi.org/10.1002/anie.200804661
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/76223
dc.identifier.wosidWOS:000263082300010
dc.information.autorucQuímica;Rojas R;S/I;1001533
dc.information.autorucQuímica;Serrano A;S/I;149349
dc.issue.numero6
dc.language.isoen
dc.nota.accesoSin adjunto
dc.pagina.final1092
dc.pagina.inicio1089
dc.publisherWILEY-V C H VERLAG GMBH
dc.revistaANGEWANDTE CHEMIE-INTERNATIONAL EDITION
dc.rightsregistro bibliográfico
dc.subjecthomogeneous catalysis
dc.subjectnickel
dc.subjectpolymerization
dc.subjectsubstituent effects
dc.subjectTRANSITION-METAL-CATALYSTS
dc.subjectLIVING POLYMERIZATION
dc.subjectNI(II) CATALYST
dc.subjectVINYL MONOMERS
dc.subjectETHYLENE
dc.subjectCOPOLYMERIZATION
dc.subjectCOMPLEXES
dc.subjectMETHYLALUMINOXANE
dc.subjectMICROSTRUCTURE
dc.subjectREACTIVITY
dc.titleNickel alpha-Keto-beta-Diimine Initiators for Olefin Polymerization
dc.typeartículo
dc.volumen48
sipa.codpersvinculados1001533
sipa.codpersvinculados149349
sipa.indexWOS
sipa.indexScopus
sipa.trazabilidadCarga SIPA;09-01-2024
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