Rhodium(I) complexes with pyridine-2-aldehyde and related Schiff-base ligands

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dc.contributor.authorOro, Luis A.
dc.contributor.authorLamata, Mario Pilar
dc.contributor.authorValderrama Caceres, Mauricio
dc.date.accessioned2019-12-28T02:45:32Z
dc.date.available2019-12-28T02:45:32Z
dc.date.issued1983
dc.description.abstractThe synthesis of [Rh(TFB)(PyCH=NR)]ClO4 by reaction of the coordinated pyridine-2-aldehyde (PyCHO) moiety of [Rh(TFB)(PyCHO)]ClO4 with primary amines is described. They are active catalysts for the transfer of hydrogen from isopropanol to acetophenone. The catalytic activity depends upon the basicity of the parent amine. Reactions with carbon monoxide and triphenylphosphine give complexes [Rh(CO)2(PyCH=NR)]ClO4, [Rh(CO)(PPh3)2(PyCH=NR)]ClO4 and [Rh(CO)(PPh3)(PyCH=NR)]ClO4.
dc.format.extent4 páginas
dc.fuente.origenSpringer
dc.identifier.doi10.1007/BF00618798
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/27140
dc.identifier.urihttp://link.springer.com/article/10.1007/BF00618798
dc.issue.numeroNo. 1
dc.language.isoen
dc.pagina.final51
dc.pagina.inicio48
dc.revistaTransition Metal Chemistryes_ES
dc.rightsacceso restringido
dc.subject.ddc510
dc.subject.deweyMatemática física y químicaes_ES
dc.subject.ods12 Responsible consuption and production
dc.subject.odspa12 Producción y consumo responsable
dc.subject.otherHidrógenoes_ES
dc.subject.otherCatalizadoreses_ES
dc.subject.otherMonóxido de carbonoes_ES
dc.subject.otherQuimica fisicaes_ES
dc.subject.otherQuímica inorgánicaes_ES
dc.titleRhodium(I) complexes with pyridine-2-aldehyde and related Schiff-base ligandses_ES
dc.typeartículo
dc.volumenVol. 8
sipa.codpersvinculados185726
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