Nucleofugality hierarchy, in the aminolysis reaction of 4-cyanophenyl 4-nitrophenyl carbonate and thionocarbonate. Experimental and theoretical study

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dc.contributor.authorMontecinos, Rodrigo
dc.contributor.authorAliaga, Margarita E.
dc.contributor.authorPavez, Paulina
dc.contributor.authorCornejo, Patricio
dc.contributor.authorSantos, Jose G.
dc.date.accessioned2025-01-20T22:18:57Z
dc.date.available2025-01-20T22:18:57Z
dc.date.issued2021
dc.description.abstractNucleophilic substitution reactions of the title compounds have been investigated with a series of secondary alicyclic amines in several solvents. The solvent, amine, and electrophilic group effects on kinetics, mechanism and nucleofugality hierarchy are discussed from experimental and theoretical studies. These studies show the mechanistic dependence on the solvent polarity; the theoretical results indicate that the relative polarization of the reactive centres (C=O and C=S) and the stabilization of the nucleofuges are the main factors in the control of the product distribution.
dc.fuente.origenWOS
dc.identifier.doi10.1039/d0nj05837h
dc.identifier.eissn1369-9261
dc.identifier.issn1144-0546
dc.identifier.urihttps://doi.org/10.1039/d0nj05837h
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/94583
dc.identifier.wosidWOS:000659259900001
dc.issue.numero26
dc.language.isoen
dc.pagina.final11505
dc.pagina.inicio11495
dc.revistaNew journal of chemistry
dc.rightsacceso restringido
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa03 Salud y bienestar
dc.titleNucleofugality hierarchy, in the aminolysis reaction of 4-cyanophenyl 4-nitrophenyl carbonate and thionocarbonate. Experimental and theoretical study
dc.typeartículo
dc.volumen45
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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