Schiff bases of pyridoxal and polyallylamine. The formation rate determining step

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dc.contributor.authordel Vado, MAG
dc.contributor.authorGorostidi, GRE
dc.contributor.authorBasagoitia, A
dc.contributor.authorBlanco, JGS
dc.contributor.authorBlanco, FG
dc.date.accessioned2024-01-10T12:08:24Z
dc.date.available2024-01-10T12:08:24Z
dc.date.issued1998
dc.description.abstractThe apparent rate constants of formation (k(1)) and hydrolysis (k(2)) of the Schiff bases formed between pyridoxal and polyallylamine has been fitted to a kinetic scheme that involve the different protonated species in the reaction medium and the individual rate constants of formation (k(1)(i)) and hydrolysis (k(2)(i)). The (k(1)(i)) values precludes an acid catalyzed intramolecular process. The effects of hydrophobic medium due to the presence of the macromolecule on the reaction is also discussed. (C) 1998 John Wiley & Sons, Inc.
dc.format.extent6 páginas
dc.fuente.origenWOS
dc.identifier.issn0538-8066
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/76388
dc.identifier.wosidWOS:000071194700001
dc.information.autorucQuímica;Santos JG;S/I;98813
dc.issue.numero1
dc.language.isoen
dc.nota.accesoSin adjunto
dc.pagina.final6
dc.pagina.inicio1
dc.publisherJOHN WILEY & SONS INC
dc.revistaINTERNATIONAL JOURNAL OF CHEMICAL KINETICS
dc.rightsregistro bibliográfico
dc.subjectWATER-DIOXANE MIXTURES
dc.subjectL-LYSINE
dc.subjectTHERMODYNAMIC PARAMETERS
dc.subjectNORMAL-HEXYLAMINE
dc.subjectN-HEXYLAMINE
dc.subjectAMINO-ACIDS
dc.subject5'-PHOSPHATE
dc.subjectHYDROLYSIS
dc.subject5'-DEOXYPYRIDOXAL
dc.subjectPOLYPEPTIDES
dc.subject.ods12 Responsible Consumption and Production
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa12 Producción y consumo responsable
dc.subject.odspa03 Salud y bienestar
dc.titleSchiff bases of pyridoxal and polyallylamine. The formation rate determining step
dc.typeartículo
dc.volumen30
sipa.codpersvinculados98813
sipa.indexWOS
sipa.indexScopus
sipa.trazabilidadCarga SIPA;09-01-2024
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